Technical Name Structural engineering of hollow fiber membranes and design of novel selective layer materials for CO₂ capture
Project Operator National Taiwan University of Science and Technology
Project Host 鍾台生
Summary
Our team focuses on developing composite hollow fiber membranes. The inner and outer layer structures were optimized to enhance the gas permeance. In parallel, we developed a continuous wetting/coating process by utilizing the immiscibility of wetting and coating solutions. A Plasma treatment was adopted to improve their interfacial compatibility, and novel selective-layer materials were synthesized and patented to overcome the permeability–selectivity trade-off relationship for CO₂ capture.
Scientific Breakthrough
A Pebax-based composite HFMs has been successfully fabricated that combines structural design, continuous processing, and interfacial control. The membrane possesses a CO₂ permeance of 1253 GPU and a CO₂/N₂ selectivity of 34.9, showing a 200% increase in CO₂ flux over other Pebax-based HFMs. MMMs consisting of organic nanofillers or silicone rubber have been synthesized to further increase CO₂ permeability by 45% or 200%, respectively, demonstrating their potential for practical CO₂ capture.
Industrial Applicability
The hollow fiber membranes developed by our group provide a high surface area, modularity, and low energy requirement, making them ideal for carbon capture in coal-fired power plants and heavy industries. Their robust structure ensures long-term stability under harsh conditions. This scalable and cost-effective membrane technology can support Taiwan’s transition to have sustainable industries with net-zero emissions.
Keyword Hollow fiber membranes Gas separation CO2 capture Net zero carbon emissions Microstructure control Continuous processing Surface modification Mixed matrix membranes Nanomaterials Sustainable technology
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  • Tsung Han Huang